ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Spectral and Magnetochemical Investigation of Titanium (III) Chloro Alkoxy Complexes with Aliphatic Alcohols

M. Zikmund, Ľ. Štepničková, and M. Kohútová

Institute of Inorganic Chemistry, Slovak Academy of Sciences, Bratislava 9

Abstract: On the basis of magnetic measurements, absorption, diffusion-reflectance, and infrared spectra of the complexes TiCl₃ • 4CH₃OH, TiCl₃ • 5CH₃OH, and products of their thermal decomposition, the conclusions are drawn about the stereochemistries of these compounds in solid state and in tetrahydrofuran solution as well. Both above mentioned complexes possess structures řrawe-[TiCl₂(CH₃OH)₄]Cl and [TiCl(CH₃OH)₅]Cl₂, while the products of their thermal decomposition are coordination polymers in which methoxide bridges occur.

Full paper in Portable Document Format: 2311-12a856.pdf

Chemical Papers 23 (11-12) 856–860 (1969)