ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Magnetic behavior of trinickel(II) and tricobalt(II) dihydrogen tetraphosphites

M. Ebert, J. Eysseltová, and M. Kohútová

Lehrstuhl für anorganische Chemie an der Naturwissenschaftlichen Fakultät der Karlsuniversität, Prag

Abstract: Magnetic susceptibilities of (NiHPO₃)₂.Ni(H₂PO₃)₂.11H₂O (I) and (CoHPO₃)₂.Co(H₂PO₃)₂.11H₂O (II) were detd. at 78, 201, 273, and 293°K., and the Weiss consts. were calcd. The magnetic moment of I is 3.27 Bohr magnetons (μB) and of II, 4.84 μB at room temp. It was detd. from the temp. dependence of the magnetic susceptibility that there is no ferromagnetism in the tested temp. interval. From the temp. dependence of the molar magnetic susceptibility, these Weiss consts. were calcd.: +6°K. for I and + 29°K. for II.

Full paper in Portable Document Format: 2211a862.pdf (in Czech)

Chemical Papers 22 (11) 862–866 (1968)