ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

The effect of ionic strength on alkaline hydrolysis and on catalyzed and spontaneous aquation of pentaamminebromocobalt(III) ion

V. Holba

Department of Physical Chemistry, Faculty of Natural Sciences, Komenský University, 801 00 Bratislava

Abstract:  In the present work the influence of the ionic strength on the rate and thermodynamic activation parameters of the alkaline hydrolysis, of the aquation catalyzed by mercury(II) ions and of the spontaneous aquation of the pentaamminebromocobalt(III) ion are investigated. The measured values are confronted with theoretical relations for the primary salt effect and with the results obtained in previous works.

Full paper in Portable Document Format: 281a17.pdf

Chemical Papers 28 (1) 17–23 (1974)