ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Role of water in the substitution of bis(2-chloroethyl) sulfide

J. Beneš

Hochschule für chemische Technologie, Pardubice

Abstract: In a kinetic study of the hydrolysis of bis(2-chloroethyl) sulfide (I) it was detd. that ionization of I was effected by interaction of it with a mol. of H₂O. The effect of the ionic force on the reaction speed in the acid and neutral medium can be explained by the fact that the conversion of 2-hydroxyethyl 2-chloroethyl sulfide into I at pH 7.0 was purely a monomol. process, while in the presence of acids it was effected by the effect of H ions on chlorohydrin.

Full paper in Portable Document Format: 1811a852.pdf (in Slovak)

Chemical Papers 18 (11) 852–863 (1964)