ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Liquidus Curves of Ideal Ionic Systems. II.

M. Malinovský

Institute of Inorganic Chemistry, Slovak Academy of Sciences, Bratislava 9

Abstract: Analysis of equations for calculation of liquidus curves in a binary simple eutectic system is performed. The equation of the slope of tangent to the liquidus curve in the melting point is derived and the relationship to the Stortenbeker correction factor is shown. Character of the liquidus curve with regard to its concavity or convexity with respect to the concentration axis is discussed. It has been found that convex parts of liquidus curves with regard to the concentration axis occur much more frequently in the ionic systems.

Full paper in Portable Document Format: 2311-12a809.pdf

Chemical Papers 23 (11-12) 809–815 (1969)