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ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Published monthly
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The Crystal Structure of Cu(H2P03)2
M. Handlovič
Institute of Inorganic Chemistry, Slovak Academy of Sciences,
Bratislava 9
Abstract: Cu(H2P03)2 crystallizes in space group P21/c with a = 7.490, b = 9.938,
с = 7.465 Å, ß = 99.6°, Z = 4. The structure was refined by means of three-
-dimensional least-squares method. The final R value for 1013 observed structure
factors is 0.115. The characteristic feature of the structure are pairs of distorted
octahedra with one common edge. These pairs are bonded together
by H2PO3- groups so that the entire structure may be considered as representing
a coordination polymer. Сu —О bonds in octahedra are 1.98, 1.97, 1.92,
1.96, 2.33, and 3.15 Å respectively.
Full paper in Portable Document Format: 266a494.pdf
Chemical Papers 26 (6) 494–501 (1972)
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