ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Contribution of interatomic repulsion forces to the broadening of vibration bands of planar XY₃ molecules

K. Sarka

Institute of Inorganic Chemistry, Slovak Academy of Sciences, 809 34 Bratislava

Abstract: The effect of short-range repulsion forces on the shape of A₁ vibration bands of planar XY₃ mols. in liq. phase is described. The repulsion forces are described by the Born-Mayer potential. Application of the perturbation theory and stochastic models of reorientation and translation of mols gives results which for a simple model of radial distribution function agree semiquant. with expt.

Full paper in Portable Document Format: 346a721.pdf

Chemical Papers 34 (6) 721–725 (1980)