ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Contribution of interatomic repulsion forces to the broadening of vibration bands of planar XY3 molecules

K. Sarka

Institute of Inorganic Chemistry, Slovak Academy of Sciences, 809 34 Bratislava

 

Abstract: The effect of short-range repulsion forces on the shape of A1 vibration bands of planar XY3 mols. in liq. phase is described. The repulsion forces are described by the Born-Mayer potential. Application of the perturbation theory and stochastic models of reorientation and translation of mols gives results which for a simple model of radial distribution function agree semiquant. with expt.

Full paper in Portable Document Format: 346a721.pdf

 

Chemical Papers 34 (6) 721–725 (1980)

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